These extended resonance stabilization possibilities explain why the redox potential of the NCoA/DHNCoA is substantially more positive than that of the monocyclic benzoyl-CoA/cyclohexa-1,5-diene-1-carboxyl-CoA redox couple (E°′ = −622 mV). Importance: Finally, aromatic compounds can be completely degraded to serve as carbon and energy sources. Organofluorides are produced as pesticides, pharmaceuticals, and other chemicals and comprise approximately one quarter of all organic compounds in the pharmaceutical and agricultural sectors; they are considered a growing class of environmentally relevant persistent pollutants. salt and (a) photochemically generated free radicals, (b) photoexcited sensitizer, and (c) electron rich compounds in the Enzymes that proceed through radical intermediates have a rich chemistry that includes functionalisation of otherwise unreactive carbon atoms, carbon-skeleton rearrangements, aromatic reductions, and unusual eliminations. BCoA or the nonphysiological electron-accepting substrate hydroxylamine stimulated the redox-dependent effects; the rates of both the overall ATPase and the autophosphatase activities of reduced BCR were increased 6-fold. Highest energy (-0.144) NBO orbital on M. Click for 3D. Nat Rev Microbiol 9: 803-816, Enzyme catalyzed radical dehydrations of hydroxy acids, Dark-operative protochlorophyllide oxidoreductase generates substrate radicals by an iron-sulphur cluster in bacteriochlorophyll biosynthesis, Differential Membrane Proteome Analysis Reveals Novel Proteins Involved in the Degradation of Aromatic Compounds in Geobacter metallireducens, A catalytically versatile benzoyl-CoA reductase, key enzyme in the degradation of methyl- and halobenzoates in denitrifying bacteria, Low potential enzymatic hydride transfer via highly cooperative and inversely functionalized flavin cofactors, Anaerobic Radical Enzymes for Biotechnology, Radical and Electron Recycling in Catalysis, Catabolic Pathways and Enzymes Involved in the Anaerobic Degradation of Polycyclic Aromatic Hydrocarbons, Reversible Biological Birch Reduction at an Extremely Low Redox Potential, ChemInform Abstract: Dearomatization Strategies in the Synthesis of Complex Natural Products, Oxygen-detoxification by dienoyl-CoA oxidase involving flavin/disulfide cofactors, The class II benzoyl‐coenzyme A reductase complex from the sulfate‐reducing Desulfosarcina cetonica, Katalyse durch Rezyklierung von Radikalen oder Elektronen, The terrestrial vertebrate fauna of Litchfield National Park, Northern Territory: Monitoring over a 6-year period and response to fire history, Development of Sustainable Biocatalytic Reduction Processes for Organic Chemists, Catabolic Pathways and Enzymes Involved in the Anaerobic Degradation of Monocyclic Aromatic Compounds, Desaromatisierungsstrategien in der Synthese strukturell komplexer Naturstoffe, The Benzoyl-Coenzyme A Reductase and 2-Hydroxyacyl-Coenzyme A Dehydratase Radical Enzyme Family, Microbial enzymology: Reduction of aromatic compounds at the negative end of the biological reduction scale, Enantioselective Enzymatic Naphthoyl Ring Reduction, ATP-Dependent Electron Activation Module of Benzoyl-Coenzyme A Reductase from the Hyperthermophilic Archaeon Ferroglobus placidus, Reduction/Hydrogenation of Aromatic Rings, Hydrocarbons and Lipids: An Introduction to Structure, Physicochemical Properties, and Natural Occurrence, An allylic ketyl radical intermediate in clostridial amino-acid fermentation, Deprotonation of Enoxy Radicals: Theoretical Validation of a 50YearOld Mechanistic Proposal, One-Electron Redox Reactions of CoASH Esters in Anaerobic Bacteria—A Mechanistic Proposal, Cyclohexa-1,5-diene-1-carboxyl-CoA hydratase, an enzyme involved in anaerobic metabolism of benzoyl-CoA in the denitrifying bacterium Thauera aromatica, A theoretical approach to the Birch reduction.

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